Note
Thesis (M.S.)--Florida Atlantic University, 1973.
Member of
Contributors
Publisher
Florida Atlantic University
Date Issued
1973
Description
The electrochemical reduction of Mo 2O4 (EDTA)^2- is studied at a mercury electrode in pH 7-10 borate and phosphate buffers utilizing the techniques
of cyclic voltammetry, chronoamperometry, and controlled potential coulometry.
The electrochemical reduction of Mo 204(EDTA)^2- is a four-electron, diffusion
controlled process in which the initial step is an irreversible two-electron
transfer. The product is a binuclear dioxo-bridged complex of Mo (III)
with EDTA. Dependence of the electrode reaction mechanism on pH, buffer
composition, and sodium ion concentration is studied . These results indicate
that a chemical protonation step occurs prior to electrochemical reduction.
A treatment of the effect of changes in double layer structure
on the protonation reaction is presented.
of cyclic voltammetry, chronoamperometry, and controlled potential coulometry.
The electrochemical reduction of Mo 204(EDTA)^2- is a four-electron, diffusion
controlled process in which the initial step is an irreversible two-electron
transfer. The product is a binuclear dioxo-bridged complex of Mo (III)
with EDTA. Dependence of the electrode reaction mechanism on pH, buffer
composition, and sodium ion concentration is studied . These results indicate
that a chemical protonation step occurs prior to electrochemical reduction.
A treatment of the effect of changes in double layer structure
on the protonation reaction is presented.
Language
Type
Form
Extent
82 p.
Subject (Topical)
Identifier
13600
Additional Information
Thesis (M.S.)--Florida Atlantic University, 1973.
Charles E. Schmidt College of Science
Date Backup
1973
Date Text
1973
Date Issued (EDTF)
1973
Extension
FAU
FAU
admin_unit="FAU01", ingest_id="ing1508", creator="staff:fcllz", creation_date="2007-07-19 01:19:58", modified_by="staff:fcllz", modification_date="2011-01-06 13:08:58"
IID
FADT13600
Organizations
Attributed name: Florida Atlantic University
Person Preferred Name
RENDA, VIRGINIA.
Graduate College
Physical Description
82 p.
application/pdf
Title Plain
ELECTROCHEMICAL REDUCTION OF A BINUCLEAR DIOXO-BRIDGED MOLYBDENUM(V) COMPLEX WITH ETHYLENEDIAMINETETRAACETATE
Use and Reproduction
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Origin Information
1973
Boca Raton, Fla.
Florida Atlantic University
Physical Location
Florida Atlantic University Libraries
Place
Boca Raton, Fla.
Sub Location
Digital Library
Title
ELECTROCHEMICAL REDUCTION OF A BINUCLEAR DIOXO-BRIDGED MOLYBDENUM(V) COMPLEX WITH ETHYLENEDIAMINETETRAACETATE
Other Title Info
ELECTROCHEMICAL REDUCTION OF A BINUCLEAR DIOXO-BRIDGED MOLYBDENUM(V) COMPLEX WITH ETHYLENEDIAMINETETRAACETATE