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Non-metal catalyzed cyclization of α-alkynyl hydrazines to form azaproline derivatives: a mechanism study

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Type: Text
Year: 2012, 2012
Member of: FAU Undergraduate Student Research
Contributors: Lepore, Salvatore D., Maity, Pradip, Nagy, Edith
Publisher: Florida Atlantic University Libraries' Digital Library [digital object]
Full Text: Non-Metal Catalyzed Cyclization of α-Alkynyl Hydrazines to Form Azaproline Derivatives: a Mechanism Study Edith Nagy, Pradip Maity and Dr. Salvatore D. Lepore Charles E. Schmidt College of Science of Florida Atlantic University Background • Synthetic …

Scalable Synthesis of 18-Crown-6 Based Lariat Ethers and Their Evaluation as Catalysts in Ester Hydolyosis

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Type: Text
Year: 2015, 2015
Member of: FAU Undergraduate Student Research
Contributors: Jana, Susovan, Lepore, Salvatore D., Suresh, Vallabh
Publisher: Florida Atlantic University Libraries: Digital Library
Description: The syntheses of various Lariat crown ethers including several not previously reported and their efficient purification are presented. The synthesis route brings together reactions from a variety of previous works leading to a robust and generalized approach to these C-pivot lariats. The main steps are condensation of functionalized diols with penta-ethylene glycol ditosylate in the presence of… more
Full Text: … Florida Atlantic University Libraries: Digital Library …

Exploring cation-π interactions in a sophomore Organic Chemistry Laboratory experiment

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Type: Text
Year: 2014, 2014
Member of: FAU Undergraduate Student Research
Contributors: Horowitz, Andrew, Lepore, Salvatore D., Rezler, Evonne, Rucco, Dominic, St. Germain, Elijah
Publisher: Florida Atlantic University Digital Library
Description: An Organic Chemistry Lab experiment is being developed and adapted from work recently published by Maity and Lepore [1] investigating the cyclization of substituted β-alkynyl hydrazines to yield azaproline derivatives. The mechanism of this reaction is putatively driven by cation-π interaction of alkynyl hydrazine with a tetrabutylammonium ion. This experiment will present students with a cutting… more
Full Text: Exploring cation-π interactions in a sophomore Organic Chemistry Laboratory experiment Andrew Horowitz*, Dominic Rucco*, Elijah St. Germain, Dr. Salvatore Lepore, Dr. Evonne Rezler Florida Atlantic University – Department of Chemistry and Biochemistry, …

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