Recent developments in phase-vanishing reactions with PTFE (Teflon®) as a phase screen

File
Publisher
Florida Atlantic University Digital Library
Date Issued
2011
EDTF Date Created
2011
Description
The Phase-Vanishing polytetrafluoroethylene (PTFE, Teflon®) method separates two reactants with a layer of semipermeable polytetrafluoroethylene (PTFE, Teflon®) tape. Expanding on previous work by Van Zee and Dragojlovic, this work investigates the use of the PV-PTFE method under solvent-free conditions and explores its value as a synthetic method for Wittig reactions to produce allenes and allenyl esters. We conducted multiple brominations, halolactonizations, and tandem Diels-Alder-halolactonizations under solvent-free conditions with largely successful results. We also synthesized an allenyl ester, as well as cis-stilbenes using benzyltriphenylphosphonium salts, but cannot report any significant advantage of the PV-PTFE method over known methods.
Note

Includes bibliography.

Language
Type
Genre
Extent
33 p.
Identifier
FA00003598
Rights

Copyright © is held by the author with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder.

Additional Information
Includes bibliography.
Thesis (B.A.)--Florida Atlantic University, Harriet L. Wilkes Honors College, 2011.
Florida Atlantic University Digital Library Collections
Date Backup
2011
Date Created Backup
2011
Date Text
2011
Date Created (EDTF)
2011
Date Issued (EDTF)
2011
Extension


FAU

IID
FA00003598
Organizations
Person Preferred Name

Pels, Kevin

author

Harriet L. Wilkes Honors College
Physical Description

online resource
33 p.
Title Plain
Recent developments in phase-vanishing reactions with PTFE (Teflon®) as a phase screen
Use and Reproduction
Copyright © is held by the author with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder.
http://rightsstatements.org/vocab/InC/1.0/
Origin Information

2011
2011
Florida Atlantic University Digital Library

Boca Raton, Fla.

Place

Boca Raton, Fla.
Title
Recent developments in phase-vanishing reactions with PTFE (Teflon®) as a phase screen
Other Title Info

Recent developments in phase-vanishing reactions with PTFE (Teflon®) as a phase screen