Synthesis and coordination chemistry of the 1,3-bis(2-pyridylimino)benz(f)isoindoline ligand

File
Publisher
Florida Atlantic University
Date Issued
1994
Description
Transition metal complexes of the mononucleating 1,3-bis(pyridylimino)isoindoline ligand (BAII) have been useful as redox catalysts and as models for naturally occurring metal centers. The redox properties of binuclear 1,3,5,7-tetra(pyridylimino)benzodipyrrole (TAII) complexes have also been investigated. Attempts to prepare 1,3,6,8-tetra(2-(4-methylpyridyl)imino)naphthodipyrrole (NTAII) using calcium chloride catalysis and solid fusion will be discussed. Divalent Cu, Ni, Zn, and Pd complexes of the mononucleating 1,3-bis(pyridylimino)benz(f)isoindoline ligand (NBAII) were prepared and the crystal structure of Cu(II)OAc(NBAII) is discussed. It is believed that the dimolybdenum NBAII complex has also been prepared. The NBAII complexes were characterized using NMR, IR, and UV-visible spectroscopy.
Note

Thesis (M.S.)--Florida Atlantic University, 1994.

Language
Type
Extent
144 p.
Identifier
15082
Additional Information
Thesis (M.S.)--Florida Atlantic University, 1994.
Date Backup
1994
Date Text
1994
Date Issued (EDTF)
1994
Extension


FAU
FAU
admin_unit="FAU01", ingest_id="ing1508", creator="staff:fcllz", creation_date="2007-07-19 03:38:29", modified_by="staff:fcllz", modification_date="2011-01-06 13:09:17"

IID
FADT15082
Issuance
monographic
Organizations
Person Preferred Name

Maehlmann, William Pierre
Graduate College
Physical Description

144 p.
application/pdf
Title Plain
Synthesis and coordination chemistry of the 1,3-bis(2-pyridylimino)benz(f)isoindoline ligand
Use and Reproduction
Copyright © is held by the author with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder.
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Origin Information

1994
monographic

Boca Raton, Fla.

Florida Atlantic University
Physical Location
Florida Atlantic University Libraries
Place

Boca Raton, Fla.
Sub Location
Digital Library
Title
Synthesis and coordination chemistry of the 1,3-bis(2-pyridylimino)benz(f)isoindoline ligand
Other Title Info

Synthesis and coordination chemistry of the 1,3-bis(2-pyridylimino)benz(f)isoindoline ligand