Note
Charles E. Schmidt College of Science
Member of
Contributors
Publisher
Florida Atlantic University
Date Issued
1993
Description
The planar, dinuclear, tridentate ligands, 1,3,5,7-tetrakis(2-pyridylimino)benzodipyrrole (TAII) and 1,3,5,7-tetrakis(4,6-dimethyl-2-pyridylimino)benzodipyrrole (DiMeTAII) were synthesized and characterized as were all intermediates characterized by both infrared and 1H-NMR spectra. Evidence is presented for the formation of Mo4(OAc)6-(DiMeTAII) (I), the dinuclear analog of Mo2(OAc)3-BAII using UV/Vis to show the delta--->delta* transition typical of the quadruple bond and for the determination of percent molybdenum which is consistent with the proposed structure. A review of recent studies into the field of quadruply bonded metal containing polymers will be discussed along with application of compound (I) in this field.
Language
Type
Form
Extent
132 p.
Subject (Topical)
Identifier
14950
Additional Information
Charles E. Schmidt College of Science
Thesis (M.S.)--Florida Atlantic University, 1993.
FAU Electronic Theses and Dissertations Collection
Date Backup
1993
Date Text
1993
Date Issued (EDTF)
1993
Extension
FAU
FAU
admin_unit="FAU01", ingest_id="ing1508", creator="staff:fcllz", creation_date="2007-07-19 03:24:47", modified_by="staff:fcllz", modification_date="2011-01-06 13:09:16"
IID
FADT14950
Issuance
monographic
Organizations
Attributed name: Florida Atlantic University
Attributed name: Charles E. Schmidt College of Science
Attributed name: Department of Chemistry and Biochemistry
Person Preferred Name
Kavanaugh, David John
Graduate College
Physical Description
132 p.
application/pdf
Title Plain
synthesis of bis(dimolybdenum)-1,3,5,7-tetrakis(2-pyridylimino) benzodipyrrole as a precursor for an inorganic, quadruple bond containing polymer
Use and Reproduction
Copyright © is held by the author with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder.
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Origin Information
1993
monographic
Boca Raton, FL
Florida Atlantic University
Physical Location
Florida Atlantic University Libraries
Place
Boca Raton, FL
Sub Location
Digital Library
Title
synthesis of bis(dimolybdenum)-1,3,5,7-tetrakis(2-pyridylimino) benzodipyrrole as a precursor for an inorganic, quadruple bond containing polymer
Other Title Info
The
synthesis of bis(dimolybdenum)-1,3,5,7-tetrakis(2-pyridylimino) benzodipyrrole as a precursor for an inorganic, quadruple bond containing polymer