Note
Thesis (M.S.)--Florida Atlantic University, 1995.
Member of
Contributors
Date Issued
1995
Description
The presence of multiply bonded dimetal units in materials offers opportunities for tuning properties of solids. Materials containing molybdenum-molybdenum quadruple bonds have recently begun being reported. This thesis reports the products of the reactions of dimethyl sulfide (DMS), acetonitrile (ACN) and acetate complexes, Mo2CI4(DMS)4, Mo2(ACN)10ABF4, and Mo2(0Ac)4
with 2,2';6,2"-terpyridine, 4'-phenyl 2,2';6,2"-terpyridine, 2,3,5,6-tetrakis (alpha-pyridyl) pyrazine and 1,3-bis(4-methylimino)isoindoline. Among these ligands, 2,3,5,6-tetrakis (alpha-pyridyl) pyrazine may lead to linear arrays of metal-metal bonds as well as other ordered structures. 1H-NMR, electronic absorption, and infrared data will be quoted to support any structural assignments.
with 2,2';6,2"-terpyridine, 4'-phenyl 2,2';6,2"-terpyridine, 2,3,5,6-tetrakis (alpha-pyridyl) pyrazine and 1,3-bis(4-methylimino)isoindoline. Among these ligands, 2,3,5,6-tetrakis (alpha-pyridyl) pyrazine may lead to linear arrays of metal-metal bonds as well as other ordered structures. 1H-NMR, electronic absorption, and infrared data will be quoted to support any structural assignments.
Language
Type
Form
Extent
153 p.
Subject (Topical)
Identifier
15212
Additional Information
Thesis (M.S.)--Florida Atlantic University, 1995.
Charles E. Schmidt College of Science
FAU Electronic Theses and Dissertations Collection
Date Backup
1995
Date Text
1995
Date Issued (EDTF)
1995
Extension
FAU
FAU
admin_unit="FAU01", ingest_id="ing1508", creator="staff:fcllz", creation_date="2007-07-19 03:54:28", modified_by="staff:fcllz", modification_date="2011-01-06 13:09:09"
IID
FADT15212
Issuance
monographic
Organizations
Attributed name: Florida Atlantic University
Attributed name: Charles E. Schmidt College of Science
Attributed name: Department of Chemistry and Biochemistry
Person Preferred Name
Hu, Chiwei
Graduate College
Physical Description
153 p.
application/pdf
Title Plain
Synthesis of new materials containing metal-metal quadruple bonds: Complexes containing 2,2';6'2''-terpyridine, 4'-phenyl-2,2';6'2''-terpyridine, 2,3,5,6-tetrakis(alpha-pryidyl)pyrazine, and 1,3-bis(4-methylimino)isoindoline
Use and Reproduction
Copyright © is held by the author with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder.
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Origin Information
1995
monographic
Physical Location
Florida Atlantic University Libraries
Sub Location
Digital Library
Title
Synthesis of new materials containing metal-metal quadruple bonds: Complexes containing 2,2';6'2''-terpyridine, 4'-phenyl-2,2';6'2''-terpyridine, 2,3,5,6-tetrakis(alpha-pryidyl)pyrazine, and 1,3-bis(4-methylimino)isoindoline
Other Title Info
Synthesis of new materials containing metal-metal quadruple bonds: Complexes containing 2,2';6'2''-terpyridine, 4'-phenyl-2,2';6'2''-terpyridine, 2,3,5,6-tetrakis(alpha-pryidyl)pyrazine, and 1,3-bis(4-methylimino)isoindoline