Note
Charles E. Schmidt College of Science
Member of
Contributors
Publisher
Florida Atlantic University
Date Issued
1979
Description
The electrochemical reduction of the cis-dioxo Mo(VI)-catechol complex, MoO2(cat2^2-, is investigated at a mercury electrode in pH 3.5-10 aqueous buffers utilizing the techniques of cyclic voltammetry and controlled potential coulometry. The reduction of MoO2(cat2^2- proceeds
by successive two-proton, one-electron and two- proton, two-electron
transfer steps which produce monomeric Mo(V) and Mo(III) species. At
pH 3.5-7 the Mo(V) monomer is unstable and undergoes dimerization. The
mechanism of the dimerization reaction and the structure of the Mo(V)
dimer produced are determined. At pH 7-10 the monomeric Mo (V) and
2- Mo(III) complexes produced by reduction of MoO2(cat2^2- are stable. A
stable Mo(IV) species is obtained upon reoxidation of the Mo( III )
monomer. The epr spectrum of the monomeric Mo(V) complex and visible
spectra of all oxidation states in alkaline solution arc reported.
by successive two-proton, one-electron and two- proton, two-electron
transfer steps which produce monomeric Mo(V) and Mo(III) species. At
pH 3.5-7 the Mo(V) monomer is unstable and undergoes dimerization. The
mechanism of the dimerization reaction and the structure of the Mo(V)
dimer produced are determined. At pH 7-10 the monomeric Mo (V) and
2- Mo(III) complexes produced by reduction of MoO2(cat2^2- are stable. A
stable Mo(IV) species is obtained upon reoxidation of the Mo( III )
monomer. The epr spectrum of the monomeric Mo(V) complex and visible
spectra of all oxidation states in alkaline solution arc reported.
Language
Type
Form
Extent
120 p.
Subject (Topical)
Identifier
13979
Additional Information
Charles E. Schmidt College of Science
Thesis (M.S.)--Florida Atlantic University, 1979.
FAU Electronic Theses and Dissertations Collection
Date Backup
1979
Date Text
1979
Date Issued (EDTF)
1979
Extension
FAU
FAU
admin_unit="FAU01", ingest_id="ing1508", creator="staff:fcllz", creation_date="2007-07-19 01:55:11", modified_by="staff:fcllz", modification_date="2011-01-06 13:09:04"
IID
FADT13979
Issuance
monographic
Organizations
Attributed name: Florida Atlantic University
Attributed name: Charles E. Schmidt College of Science
Attributed name: Department of Chemistry and Biochemistry
Person Preferred Name
CHARNEY, LYNN MARLENE.
Graduate College
Physical Description
120 p.
application/pdf
Title Plain
ELECTROCHEMISTRY OF MONOMERIC MOLYBDENUM (VI)-, (V)-, (IV)- AND (III)- CATECHOL COMPLEXES IN AQUEOUS MEDIA
Use and Reproduction
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Origin Information
1979
monographic
Boca Raton, Fla.
Florida Atlantic University
Physical Location
Florida Atlantic University Libraries
Place
Boca Raton, Fla.
Sub Location
Digital Library
Title
ELECTROCHEMISTRY OF MONOMERIC MOLYBDENUM (VI)-, (V)-, (IV)- AND (III)- CATECHOL COMPLEXES IN AQUEOUS MEDIA
Other Title Info
ELECTROCHEMISTRY OF MONOMERIC MOLYBDENUM (VI)-, (V)-, (IV)- AND (III)- CATECHOL COMPLEXES IN AQUEOUS MEDIA