Note
Thesis (M.S.)--Florida Atlantic University, 1977.
Member of
Contributors
Publisher
Florida Atlantic University
Date Issued
1977
Description
The ferrocenylrnethylation of the following compounds was studied
using (ferrocenylmethyl)trimethylammonium iodide: 1, 1-di(p-anisyl)-
ethene (I), 1, 1-di(p- anisyl)propene (II), 1- (p- anisyl)-1-phenylethene
(III), 1, 1- diphenylethene (IV), 1, 1- di(p- dimethylaminophenyl )ethene
(V) and 1, 1-di(p-dimethylaminophenyl)propene (VI). I is ferrocenylmethylated
exclu,sively on its side-chain, one or both vinyl hydrogens
being replaced by ferrocenylmethyl groups depending on the ratio of
ferrocenylmethylating agent to I, concentration of the reaction mixture,
reaction time, solvent and temperature. II is substituted only on its
side-chain to give a mono-ferrocenylmethylated product. III is ferrocenylmethylated
slowly. IV fails to react. Mono-ferrocenylmethylation
of V occurs principally on its side- chain; more extensive ferrocenylmethylation
occurs both on the side-chain and on the rings at the
position ortho to dimethylamino. VI reacts quite indiscriminately both
on the side-chain and on the rings.
using (ferrocenylmethyl)trimethylammonium iodide: 1, 1-di(p-anisyl)-
ethene (I), 1, 1-di(p- anisyl)propene (II), 1- (p- anisyl)-1-phenylethene
(III), 1, 1- diphenylethene (IV), 1, 1- di(p- dimethylaminophenyl )ethene
(V) and 1, 1-di(p-dimethylaminophenyl)propene (VI). I is ferrocenylmethylated
exclu,sively on its side-chain, one or both vinyl hydrogens
being replaced by ferrocenylmethyl groups depending on the ratio of
ferrocenylmethylating agent to I, concentration of the reaction mixture,
reaction time, solvent and temperature. II is substituted only on its
side-chain to give a mono-ferrocenylmethylated product. III is ferrocenylmethylated
slowly. IV fails to react. Mono-ferrocenylmethylation
of V occurs principally on its side- chain; more extensive ferrocenylmethylation
occurs both on the side-chain and on the rings at the
position ortho to dimethylamino. VI reacts quite indiscriminately both
on the side-chain and on the rings.
Language
Type
Form
Extent
207 p.
Subject (Topical)
Identifier
13837
Additional Information
Thesis (M.S.)--Florida Atlantic University, 1977.
Date Backup
1977
Date Text
1977
Date Issued (EDTF)
1977
Extension
FAU
FAU
admin_unit="FAU01", ingest_id="ing1508", creator="staff:fcllz", creation_date="2007-07-19 01:42:09", modified_by="staff:fcllz", modification_date="2011-01-06 13:09:05"
IID
FADT13837
Issuance
monographic
Organizations
Attributed name: Florida Atlantic University
Person Preferred Name
FERNANDEZ, ROSA MIRTA
Graduate College
Physical Description
207 p.
application/pdf
Title Plain
FERROCENYLMETHYLATION OF 1,1-DIARYLALKENES
Use and Reproduction
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Origin Information
1977
monographic
Boca Raton, Fla.
Florida Atlantic University
Physical Location
Florida Atlantic University Libraries
Place
Boca Raton, Fla.
Sub Location
Digital Library
Title
FERROCENYLMETHYLATION OF 1,1-DIARYLALKENES
Other Title Info
FERROCENYLMETHYLATION OF 1,1-DIARYLALKENES