Note
Thesis (M.S.)--Florida Atlantic University, 1982.
Member of
Contributors
Publisher
Florida Atlantic University
Date Issued
1982
Description
Catalytic reductions of NO2, ClO3, and BrO3 by aqueous molybdenum-catechol complexes at pH 9 are investigated by electrochemical techniques. Binding of substrate to the molybdenum center occurs
through the unshared electron pair of the substrate central atom.
The molybdenum (V) and - (IV) oxidation states are catalytically
active, while Mo(III) is not. A single mechanism for the reaction
of Mo(V) with all three substrates is proposed, and a rate expression
for this reaction is derived. General features of the Mo (IV) reaction
are describec. Nitrous oxide was identified by gas chromatography
as a product of the Mo(V) - NO2 reaction.
through the unshared electron pair of the substrate central atom.
The molybdenum (V) and - (IV) oxidation states are catalytically
active, while Mo(III) is not. A single mechanism for the reaction
of Mo(V) with all three substrates is proposed, and a rate expression
for this reaction is derived. General features of the Mo (IV) reaction
are describec. Nitrous oxide was identified by gas chromatography
as a product of the Mo(V) - NO2 reaction.
Language
Type
Form
Extent
104 p.
Subject (Topical)
Identifier
14118
Additional Information
Thesis (M.S.)--Florida Atlantic University, 1982.
Charles E. Schmidt College of Science
FAU Electronic Theses and Dissertations Collection
Date Backup
1982
Date Text
1982
Date Issued (EDTF)
1982
Extension
FAU
FAU
admin_unit="FAU01", ingest_id="ing1508", creator="staff:fcllz", creation_date="2007-07-19 02:08:00", modified_by="staff:fcllz", modification_date="2011-01-06 13:09:06"
IID
FADT14118
Issuance
monographic
Organizations
Attributed name: Florida Atlantic University
Attributed name: Charles E. Schmidt College of Science
Attributed name: Department of Chemistry and Biochemistry
Person Preferred Name
LAHR, SUZANNE KAY
Graduate College
Physical Description
104 p.
application/pdf
Title Plain
ELECTROCATALYTIC REACTIONS OF OXO ANIONS WITH MOLYBDENUM - CATECHOL COMPLEXES
Use and Reproduction
Copyright © is held by the author with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder.
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Origin Information
1982
monographic
Boca Raton, FL
Florida Atlantic University
Physical Location
Florida Atlantic University Libraries
Place
Boca Raton, FL
Sub Location
Digital Library
Title
ELECTROCATALYTIC REACTIONS OF OXO ANIONS WITH MOLYBDENUM - CATECHOL COMPLEXES
Other Title Info
ELECTROCATALYTIC REACTIONS OF OXO ANIONS WITH MOLYBDENUM - CATECHOL COMPLEXES