Note
Thesis (M.S.)--Florida Atlantic University, 1972.
Member of
Contributors
Publisher
Florida Atlantic University
Date Issued
1972
Description
In this research it was found that strongly
nucleophilic aromatic compounds, like phenol, resorcinol,
anisole, N,N-dimethylaniline, mes.l.tylene, thiophene,
thianaphthene, N-methylpyrrole, indole and ferrocene, are
ferrocenylmethylated on a ring-carbon by (ferrocenylmethyl)-
trimethylammonium iodide. The ferrocenylmethylation of aniline, N-methylaniline
and acetanilide yielded N-, o- and p-ferrocenylmethylated
products. The N-ferrocenylmethylated compounds have been
shown to undergo acid catalyzed intermolecular rearrangements
to their corresponding o- and p-ferrocenylmethyl
isomers. NMR was especially useful in structure analysis.
nucleophilic aromatic compounds, like phenol, resorcinol,
anisole, N,N-dimethylaniline, mes.l.tylene, thiophene,
thianaphthene, N-methylpyrrole, indole and ferrocene, are
ferrocenylmethylated on a ring-carbon by (ferrocenylmethyl)-
trimethylammonium iodide. The ferrocenylmethylation of aniline, N-methylaniline
and acetanilide yielded N-, o- and p-ferrocenylmethylated
products. The N-ferrocenylmethylated compounds have been
shown to undergo acid catalyzed intermolecular rearrangements
to their corresponding o- and p-ferrocenylmethyl
isomers. NMR was especially useful in structure analysis.
Language
Type
Form
Extent
187 p.
Subject (Topical)
Identifier
13482
Additional Information
Thesis (M.S.)--Florida Atlantic University, 1972.
Charles E. Schmidt College of Science
Date Backup
1972
Date Text
1972
Date Issued (EDTF)
1972
Extension
FAU
FAU
admin_unit="FAU01", ingest_id="ing1508", creator="staff:fcllz", creation_date="2007-07-19 01:09:14", modified_by="staff:fcllz", modification_date="2011-01-06 13:08:48"
IID
FADT13482
Issuance
monographic
Organizations
Attributed name: Florida Atlantic University
Person Preferred Name
PENNIE, JOHN THOMAS.
Graduate College
Physical Description
187 p.
application/pdf
Title Plain
FERROCENYLMETHYLATION OF AROMATIC COMPOUNDS
Use and Reproduction
Copyright © is held by the author with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder.
http://rightsstatements.org/vocab/InC/1.0/
Origin Information
1972
monographic
Boca Raton, Fla.
Florida Atlantic University
Physical Location
Florida Atlantic University Libraries
Place
Boca Raton, Fla.
Sub Location
Digital Library
Title
FERROCENYLMETHYLATION OF AROMATIC COMPOUNDS
Other Title Info
FERROCENYLMETHYLATION OF AROMATIC COMPOUNDS