Corrosion and anti-corrosives

This study investigates corrosion initiation and propagation in instrumented specimens obtained from segments of dry-cast reinforced concrete pipes. Potential, LPR and EIS measurements were carried out. During the propagation stage in different exposures, reinforcement eventually reached negative potentials values, which suggest mass transfer limitations. So far these specimens show no visual signs of corrosion such as cracks or corrosion products with one exception; where corrosion products have reached the surface. Moreover, the apparent corrosion rate values obtained suggest high corrosion rate. No crack appearance so far, could be explained by the high porosity of the specimens; the corrosion products are filling these pores. It is speculated that although, there might be mass transfer limitations present, the current demanded by the anode is being balanced by a larger cathode area due to macrocell effects, since the high moisture conditions likely reduced the concrete resistivity and increased the throwing power.

A cyclic polarization procedure was designed to evaluate the pitting potentials of high performance stainless steels in synthetic concrete pore water at different chloride concentrations. Cyclic polarization scans were performed on high performance stainless steel reinforcements, S32201, S32305 and S32205. Pitting initiation was observed below the oxygen evolution potential for high chloride concentrations. S32201 and S32304 showed the presence of metastable pitting before reaching its pitting potential. Pitting resistance performance, based on cyclic polarization, was consistent with each material's respective Pitting Resistance Equivalent Number (PREN) value. For S32201 and S32304, pitting potential decreased as the chloride concentration increased, whereas S32205 did not pit at the chloride concentrations tested.

The Center for Ocean Energy Technology at Florida Atlantic University is developing an ocean energy turbine system to investigate the feasibility of harnessing Florida's Gulf Stream current kinetic energy and transforming it into a usable form. The turbine system has components which are prone to marine corrosion given the materials they are made of and to the harsh environment they will be exposed to. This study assumes a two-part system composed of a coating system acting as a barrier and sacrificial anode cathodic protection which polarizes the metal structures to a potential value where corrosion is significantly reduced. Several configurations (varying in anode quantity, size and location) were considered in order to cathodically protect the structures with various coating qualities (poor, good and excellent). These cases were modeled and simulated via Boundary Element Method software and analyzed so as to assess the most appropriate design.