Environmental aspects

The world currently has more people living in cities than in rural areas. In the United States this is no exception, and as a result government policy is focusing on the supply of 'green' jobs that help repair and expand its infrastructure in an attempt to help curb non-renewable resource use. The expansion of public transportation throughout the country is one facet of the multi-pronged US government policy. In the tri-county area of South Florida (Palm Beach County, Broward County, and Miami-Dade County) a research study known as the South Florida East Coast Corridor Transit Analysis (SFECCTA) entered Phase 2 in January 2009. This study looks at incorporating the FEC freight corridor which transverses the downtown areas of 47 cities into a major North- South commuter system. This system would also supplement the existing commuter Tri- Rail corridor. The proposed methodology in this manuscript attempts to address the issue of providing an adaptable, efficient and convenient public transportation in a low to medium density environment where the automobile is the preferred mode of travel. Emphasis is placed on connecting existing origin and destination locations in and around the greater West Palm Beach metropolitan area in Palm Beach County, FL. The goal of the methodology is to establish potential routes that will connect high amounts of residence to places of social interaction, consumption, employment, and the proposed SFECCTA regional transportation system with Light Rail Transit as the end goal. As a result the proposed corridors focus on creating dedicated and shared right of ways that already exist via the road network. The discussion and conclusion provide methodology successes, improvements, and economic development recommendations.

Management of water resources has become more complex in recent years as a result of changing attitudes towards sustainability and the attribution of greater attention to environmental issues, especially under a scenario of water scarcity risk introduced by climate changes and anthropogenic pressures. This thesis addresses the conflicts in optimizing multi-purpose hydropower operations under an environment where objectives are often conflicting and uncertain. Mathematical programming formulations can be used to achieve flexible, feasible and optimal operation and planning solutions to satisfy expectations of multiple stake-holders, including regulatory environmental compliance and sustainability. Innovative optimization models using MINLP with binary variables, fuzzy set theory, partial constraint satisfaction and multi-objective formulations incorporating unit commitment problem and adaptive real-time operations are developed and applied to a real life case study. These methodologies provide advances and valuable insights on optimal operations of hydropower systems under uncertain decision making environments.

This study focuses on two main broad areas of active research on climate: climate variability and climate change and their implications on regional precipitation characteristics. All the analysis is carried out for a climate change-sensitive region, the state of Florida, USA. The focus of the climate variability analysis is to evaluate the influence of individual and coupled phases (cool and warm) of Atlantic multidecadal oscillation (AMO) and El Niäno southern oscillation (ENSO) on regional precipitation characteristics. The two oscillations in cool and warm phases modulate each other which have implications on flood control and water supply in the region. Extreme precipitation indices, temporal distribution of rainfall within extreme storm events, dry and wet spell transitions and antecedent conditions preceding extremes are evaluated. Kernel density estimates using Gaussian kernel for distribution-free comparative analysis and bootstrap sampling-based confidence intervals are used to compare warm and cool phases of different lengths. Depth-duration-frequency (DDF) curves are also developed using generalized extreme value (GEV) distributions characterizing the extremes. ... This study also introduces new approaches to optimally select the predictor variables which help in modeling regional precipitation and further provides a mechanism to select an optimum spatial resolution to downscale the precipitation projections. New methods for correcting the biases in monthly downscaled precipitation projections are proposed, developed and evaluated in this study. The methods include bias corrections in an optimization framework using various objective functions, hybrid methods based on universal function approximation and new variants.

Since the United States Environmental Protection Agency (USEPA) began requiring landfills to implement a leachate collection system in 1991, the proper disposal of leachate has become a growing concern. The potential toxicity of landfill leachate will contaminate groundwater and soil if not managed properly. Research has been made in efforts to manage leachate in a cost-effective, single treatment process. Photocatalytic oxidation is an advanced oxidation process (AOP) which has shown ability to reduce toxicity of an array of leachate constituents including organics, inorganics and heavy metals. The purpose of this manuscript is to scale up the batch scale study of TiO2 photocatalytic degradation of leachate utilizing a pilot scale falling film reactor. In this research project, the use of UV/TiO2 for the removal of chemical oxygen demand (COD), ammonia, alkalinity and color will be studied in order to optimize catalyst dosage, determine pH effects and reaction kinetics and develop preliminary cost estimates.

The gorgonian Briareum asbestinum is widely studied because it possesses highly oxygenated novel structures, many of which exhibit useful biological activities. Recently, two new briarane diterpenoids, briareolate esters J and K, together with two known briareolate esters have been isolated from a specimen of Briareum asbestinum collected off the coast of Boca Raton, Florida. The method used was a 96-well plate real-time cell electronic sensing (RT-CES) system to discover compounds that impact human embryonic stem cell growth. The compounds were isolated using reversed phase polystyrene divinylbenzene chromatographic support HP20ss followed by normal phased HPLC using a luna silica column. The structures of the compounds were established though the interpretation of spectroscopic data. Activity testing was conducted against hESCs (BG02) with briareolate ester J showing no inhibition activity and briareolate ester K showing mild activity with an EC50 value of 25 (So(BM. These results confirm that the exact confirmation and existence of the (E,Z)-dienone is related to the activity that was observed with the previously isolated briareolate esters L and M.

This thesis focuses on evaluation of joint occurrence of extreme precipitation and streamflow events at several hydrologic structures in South Florida. An analysis of twelve years storm events and their corresponding peak streamflow events during wet and dry season including annual peaks considering two seasons was performed first. Dependence analysis using time series data of precipitation and streamflow was carried out next. The analysis included use of storm events with different temporal lags from the time of occurrence of peak streamflow events. Bi-variate joint probability was found to be appropriate to analyze the joint occurrence of events. Evaluation of joint exceedence probabilities under two phases of Atlantic multidecadal oscillation (AMO) influencing south Florida was also evaluated. All methodologies are evaluated for application using observations at several structures in the case study region to provide advances and valuable insights on joint extremes of precipitation and streamflows.

Urban green space plays a vital role in the stability of the environment. Green spaces are increasingly becoming an integral part of the efforts to promote sustainability because of the different areas of benefits they provide. Sustainable city ranking systems were used to identify the most sustainable urban extents within the US. Landsat TM 4-5 imagery and textural classification are used as techniques in identifying, classifying and analyzing urban green spaces within nineteen urban extents. Patch analyst was used to analyze the location, structure and fragmentation green spaces within each urban extent. The aim is to determine to what degree urban green spaces can be considered to be an integral part of the sustainability of sustainable urban extents across the US and ascertain whether or not more sustainable urban extents do have more urban green spaces. The results of the study have shown that urban extents that are ranked highly v on sustainable ranking systems do not necessarily have to have large proportion of green spaces. Results have also shown that urban extents that are ranked high on sustainable rankings will not necessarily be affected by increase in population or decrease in urban green space. Finally human modified green spaces have simple geometric shapes compared to natural unaltered green spaces that have more complex geometric shapes.

the decades after World War II the United States became the most prosperous nation in the world. Yet, that prosperity and growth had a negative impact on the environmental quality of the nation. By the mid 1960s there was a rise in concern over environmental issues in the American public. Consequently, President Richard M. Nixon in his determination to give the American people what they sought decided to enact policies to bring the environmental crisis to an end. Among the environmental policies of the Nixon Administration was the Clean Air Act of 1970, a highly controversial piece of legislation that placed tough regulations on the automobile industry. Due to the significant role of the auto industry in the American economy, and Nixon's concerns over reelection, there were two major shifts in business/government relations during this era. The first one was characterized by determination to protect the environment with little attention to complaints from the industry. The second one was about protecting the profitability of the industry while giving little attention to environmental problems.

Increasing sea levels have the potential to place important portions of the infrastructure we rely on every day at risk. The transportation infrastructure relies on roads, airports, and seaports to move people, services, and goods around in an ever connected global economy. Any disturbances of the transportation modes have reverberating effects throughout the entire economic spectrum. The effects include delays, alterations of routes, and possible changes in the origin and destinations of services and goods. The purpose of this project is to develop an improved methodology for a sea level rise scenario vulnerability assessment model. This new model uses the groundwater elevation as a limiting factor for soil storage capacity in determining previously underestimated areas of vulnerability. The hope is that early identification of vulnerability will allow planners and government officials an opportunity to identify and either remediate or create alternative solutions for vulnerable land areas before high consequence impacts are felt.

Significant changes in climate and their impacts are now visible in various places around the globe and are expected to become more evident in the coming decades. For each increase in temperature, there are environmental and societal consequences. It has important implications for existing water resources systems as well as for future water resources planning and management. Water accounting (identifying, quantifying and reporting information of water flow in a system) is the first step towards formulating productive and sustainable water management strategies in a region. Thus, water balance models could be an empowering tool for water resource managers to prepare for and mitigate the effects of climate change on their local hydrologic resources. This thesis offers an insight into how such a tool can be used to assess and predict future stream flow trends in an effort to mitigate or manage any potential effects.